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https://disruptedphysician.blog/2017/06/05/breaking-really-bad-25-years-before-walter-white-by-josh-bloom-dupont-chemist-michael-hovey-synthesizes-3-methyl-fentanyl-in-1985-and-ushers-in-designer-drugs-that-kill/
Breaking Really Bad, 25 Years Before Walter White--by Josh Bloom (Dupont chemist Michael Hovey synthesizes 3-methyl fentanyl in 1985 and ushers in "designer-drugs" that kill)